Synthesis of aromatic β-keto esters via a carbonylative Suzuki–Miyaura coupling reaction of α-iodo esters with arylboronic acids†
Shuhei Sumino,Takahito Ui,Ilhyong Ryu
Organic Chemistry Frontiers Pub Date : 07/14/2015 00:00:00 , DOI:10.1039/C5QO00185D
Abstract
Aromatic β-keto esters were synthesized via a carbonylative cross-coupling reaction of alkyl iodides and arylboronic acids in the presence of a catalytic amount of Pd catalyst. A cooperative radical and Pd-catalyzed mechanism is proposed.
