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The nature of the counter-anion can determine the rate of water exchange in a metal aqua complex†
Alessandro Barge,Mauro Botta,David Parker,Horst Puschmann
Chemical Communications Pub Date : 05/16/2003 00:00:00 , DOI:10.1039/B302211K
Abstract

The nature of the counter-anion determines the water exchange rate for a series of cationic gadolinium complexes in aqueous solution, as a consequence of the ordering effect that the anion imposes on the structure of the second hydration sphere.

Graphical abstract: The nature of the counter-anion can determine the rate of water exchange in a metal aqua complex
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