960化工网
The quest for silylhydroboranes: (Me3Si)3SiBH2†‡
Henning Arp,Christoph Marschner,Judith Baumgartner
Dalton Transactions Pub Date : 07/01/2010 00:00:00 , DOI:10.1039/C0DT00096E
Abstract

Reaction of BH3·NEt3 with tris(trimethylsilyl)silylpotassium yielded the respective silylboranate. Abstraction of a hydride with B(C6F5)3 led to the neutral silylborane, which could be derivatised as an Et3N adduct. Treatment of the boranate with Cp2Ti(btmsa) resulted in exchange of THF coordinating to potassium by Cp2Ti(btmsa).

Graphical abstract: The quest for silylhydroboranes: (Me3Si)3SiBH2
平台客服
平台客服
平台在线客服