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Theoretical modeling of electrochemical nucleation and growth of a single metal nanocluster on a nanoelectrode
Vladimir A. Isaev,Olga V. Grishenkova
RSC Advances Pub Date : 02/14/2020 00:00:00 , DOI:10.1039/D0RA00608D
Abstract

Theory of the initial stages of electrochemical formation and growth of a single metal nanocluster on an indifferent nanoelectrode has been developed and analyzed. General theoretical time dependences of the current and nanocluster size have been presented for the case of diffusion controlled growth at potentio- and galvanostatic deposition, and cyclic voltammetry.

Graphical abstract: Theoretical modeling of electrochemical nucleation and growth of a single metal nanocluster on a nanoelectrode
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