960化工网
A well-defined low-valent cobalt catalyst Co(PMe3)4 with dimethylzinc: a simple catalytic approach for the reductive dimerization of benzyl halides†
Brendan J. Fallon,Vincent Corcé,Muriel Amatore,Corinne Aubert,Fabrice Chemla,Franck Ferreira,Alejandro Perez-Luna,Marc Petit
New Journal of Chemistry Pub Date : 11/16/2016 00:00:00 , DOI:10.1039/C6NJ03265F
Abstract

Herein, we report the first catalytic version of a cobalt-catalysed reductive homocoupling of benzyl halides which proceeds with low catalyst loadings (0.5 to 5 mol%). By synthetizing each cobalt intermediate we demonstrate that reaction proceeds through two single electron transfers (SET) and that dimethylzinc is only involved in the regeneration of the catalytic species.

Graphical abstract: A well-defined low-valent cobalt catalyst Co(PMe3)4 with dimethylzinc: a simple catalytic approach for the reductive dimerization of benzyl halides
平台客服
平台客服
平台在线客服