The remarkable catalytic activity of ultra-small free-CeO2 nanoparticles in selective carbon–carbon bond formation reactions in water at room temperature†,10.1039/C5NJ00500K

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

The remarkable catalytic activity of ultra-small free-CeO2 nanoparticles in selective carbon–carbon bond formation reactions in water at room temperature†

New Journal of Chemistry Pub Date : 05/06/2015 00:00:00 , DOI:10.1039/C5NJ00500K

Abstract

A simple and efficient protocol for selective bis-Michael addition and mono-allylation of active methylene compounds has been demonstrated using ultra-small (size ∼5 nm) uncapped cerium oxide nanoparticles (free-CeO₂ NPs) as a reusable catalyst in water at room temperature. The free-CeO₂ NPs were characterized by powder XRD, TEM and XPS studies. Free-CeO₂ NPs efficiently catalyzed both the reactions and produced good to excellent yields of products.