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A zeolite-like MOF based on a heterotritopic linker of imidazolyl, carboxyl and pyridine with a long-sought uks net on Schwarz's D-surface†
Chun-Rong Ye,Ji Zheng,Mian Li,Xiao-Chun Huang
Chemical Communications Pub Date : 07/16/2018 00:00:00 , DOI:10.1039/C8CC03484B
Abstract

The title MOF features a potential uninodal zeolite net, uks, which has never been found for real zeolites or zeolite-like MOFs. This rare structure exhibits specific anion binding of N3 over SCN in water, which reverses the Hofmeister series.

Graphical abstract: A zeolite-like MOF based on a heterotritopic linker of imidazolyl, carboxyl and pyridine with a long-sought uks net on Schwarz's D-surface
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