960化工网
Triazole- and triazolium-containing porphyrin-cages for optical anion sensing†
Lydia C. Gilday,Nicholas G. White,Paul D. Beer
Dalton Transactions Pub Date : 04/05/2012 00:00:00 , DOI:10.1039/C2DT30124E
Abstract

Triazole and triazolium groups have been integrated into a zinc(II) metalloporphyrin-based structural framework to produce two porphyrin-cages for anion sensing applications. UV/visible spectroscopic titration investigations reveal both host systems exhibit strong anion binding affinities, with the positively-charged triazolium-porphyrin cage capable of colorimetric sensing halides, fluoride and chloride, and oxoanions in acetonewater solvent mixtures.

Graphical abstract: Triazole- and triazolium-containing porphyrin-cages for optical anion sensing
平台客服
平台客服
平台在线客服