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Tuning uracil derivatives for the AIE-based detection of pyrene at a nano-molar level: single-crystal X-ray structure and DFT support†
Mahuya Banerjee,Milan Ghosh,Sabyasachi Ta,Subhasis Ghosh,Debasis Das
New Journal of Chemistry Pub Date : 08/12/2020 00:00:00 , DOI:10.1039/D0NJ03024D
Abstract

Single crystal X-ray structurally characterized azo-uracil derivative (L) is explored for the selective detection of pyrene via aggregation-induced emission (AIE) with 99-fold fluorescence enhancement. In the presence of pyrene, non-fluorescent L emits green light and allows pyrene detection to as low as 3.6 × 10−9 M. Three model probes (L1, L2 and L3) were employed to support the proposed sensing mechanism. Further, silica-immobilized L efficiently removes pyrene from its reservoir.

Graphical abstract: Tuning uracil derivatives for the AIE-based detection of pyrene at a nano-molar level: single-crystal X-ray structure and DFT support
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