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Two halosesquiterpenes from Laurencia composita†
Feng-Ping Miao,Xiao-Rui Liang,Bin-Gui Wang,Nai-Yun Ji
RSC Advances Pub Date : 12/04/2012 00:00:00 , DOI:10.1039/C2RA23101H
Abstract

Two new chamigrane sesquiterpenes, yicterpenes A (1) and B (2) each with an unprecedented halogenation at C-9 and a hemiketal unit at C-10, were isolated from the marine red alga Laurencia composita. The structures and absolute configurations of them were identified by NMR, ECD, and mass spectrometric methods as well as quantum chemical calculations. Compound 1 with a chlorination at C-9 was more active against some tested marine-derived organisms than 2 with a bromination at C-9.

Graphical abstract: Two halosesquiterpenes from Laurencia composita
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