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Yttrium metalloceneborane chemistry: isolation of 9-BBN substitution and coordination complexes in a single crystal, {(C5Me5)2Y[η3-C3H4(BC8H14)]} and {(C5Me5)2Y(μ-H)2BC8H14}
William J. Evans,Sara E. Lorenz,Joseph W. Ziller
Chemical Communications Pub Date : 09/26/2007 00:00:00 , DOI:10.1039/B709841C
Abstract

(C5Me5)2Y(η3-C3H5) reacts with 9-borabicyclo[3.3.1]nonane, 9-BBN, to form single crystals containing both a borane-substituted allyl complex, (C5Me5)2Y[η3-C3H4(BC8H14)], and a borohydride, (C5Me5)2Y(μ-H)2BC8H14, that can be synthesized directly from 9-BBN and the yttrium hydride, [(C5Me5)2YH]x.

Graphical abstract: Yttrium metallocene borane chemistry: isolation of 9-BBN substitution and coordination complexes in a single crystal, {(C5Me5)2Y[η3-C3H4(BC8H14)]} and {(C5Me5)2Y(μ-H)2BC8H14}
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