Variable coordination chemistry of the phospha(iii)guanidinate anion; application as a metal-functionalised phosphine ligand†
Martyn P. Coles,Peter B. Hitchcock
Chemical Communications Pub Date : 10/24/2002 00:00:00 , DOI:10.1039/B209026K
Abstract
Structural investigation of Li-complexes of the phospha(III)guanidinate anion [Ph2PC{NiPr}2]− revealed variable coordination to lithium; synthesis of the dimethyl aluminium compound, (Ph2PC{NiPr}2)AlMe2, which behaves as a metal-functionalised phosphineligand towards platinum, is reported.
