Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules; host–guest complexation with γ-cyclodextrin†,10.1039/C9CC07678F

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Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules; host–guest complexation with γ-cyclodextrin†

Suzan El Anwar,Barbara Begaj,Maksim A. Samsonov,Zdeňka Růžičková,Josef Holub,Dmytro Bavol,Werner M. Nau,Detlef Gabel,Bohumír Grűner

Chemical Communications Pub Date : 10/21/2019 00:00:00 , DOI:10.1039/C9CC07678F

Abstract

We report the modification of the 2-ammonio group at halogenated decaborate ions with 2,3-epoxypropane, the product of which reacts readily with nucleophiles to form previously inaccessible coupling of polyhedra with organic molecules and materials. We demonstrate that these ions present a good binding motif in supramolecular chemistry.