Water-soluble supramolecular bowls formed by intra-clipping of resorcin[4]arene-based ligands with Pd(ii) ions†
Seong Jin Park,Dong Mok Shin,Shigeru Sakamoto,Kentaro Yamaguchi,Young Keun Chung,Myoung Soo Lah
Chemical Communications Pub Date : 03/19/2003 00:00:00 , DOI:10.1039/B212855A
Abstract
Bowl-shaped superstructures have been constructed by intra-clipping of resorcin[4]arene derivatives with two equivalents of (en)Pd(NO3)2 in water. The binding phenomena of the aromatic carboxylates were proven to be both enthalpically and entropically favoured.