Visible light-promoted NH-halogenation of sulfoximines with dichloromethane or dibromomethane†
Chenyang Wang,Peng Shi,Carsten Bolm
Organic Chemistry Frontiers Pub Date : 03/31/2021 00:00:00 , DOI:10.1039/D1QO00382H
Abstract

In visible light, dichloro- and dibromomethane are the halogen sources for converting NH-sulfoximines to their corresponding N-halo derivatives via an in situ formed sulfoximidoyl-containing hypervalent iodine reagent. The reactions proceed in air and are catalyst- and additive-free. The products are obtained in good to excellent yields.

Graphical abstract: Visible light-promoted NH-halogenation of sulfoximines with dichloromethane or dibromomethane