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WCl6 as an efficient, heterogeneous and reusable catalyst for the preparation of 14-aryl-14H-dibenzo[a,j]xanthenes with high TOF†
Mohammad Ali Zolfigol,Ahmad Reza Moosavi-Zare,Parastoo Arghavani-Hadi,Abdolkarim Zare,Vahid Khakyzadeh,Ghasem Darvishi
RSC Advances Pub Date : 02/22/2012 00:00:00 , DOI:10.1039/C2RA00014H
Abstract

An efficient solvent-free protocol for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes from β-naphthol and arylaldehydes using WCl6 as a reusable catalyst is reported. The turn over frequency (TOF) value of the catalyst is several times higher than that of the previously reported catalysts. A clean reaction, simple purification, short reaction time and high yield are some other advantages of this work.

Graphical abstract: WCl6 as an efficient, heterogeneous and reusable catalyst for the preparation of 14-aryl-14H-dibenzo[a,j]xanthenes with high TOF
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