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Cross coupling of alkylsilicates with acyl chlorides via photoredox/nickel dual catalysis: a new synthesis method for ketones†
Etienne Levernier,Vincent Corcé,Louise-Marie Rakotoarison,Adrien Smith,Mengxue Zhang,Stephanie Ognier,Michael Tatoulian,Cyril Ollivier,Louis Fensterbank
Organic Chemistry Frontiers Pub Date : 02/27/2019 00:00:00 , DOI:10.1039/C9QO00092E
Abstract

Photoredox/nickel dual catalysis using easily oxidized bis-catecholato hypercoordinated silicon derivatives as radical sources and acyl chlorides as electrophiles allows a new method of formation of dialkyl and alkyl-aryl ketones as well as dibenzyl ketones which are less easily accessed. Flow chemistry can be used.

Graphical abstract: Cross coupling of alkylsilicates with acyl chlorides via photoredox/nickel dual catalysis: a new synthesis method for ketones
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