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Cu(OAc)2-promoted reaction of [60]fullerene with primary amines or diamines†
Xin-Wei Lu,Meng-Lei Xing,Chun-Bao Miao,Jia-Xing Li,Xiao-Qiang Sun,Hai-Tao Yang
Organic & Biomolecular Chemistry Pub Date : 07/02/2015 00:00:00 , DOI:10.1039/C5OB01048A
Abstract

The Cu(OAc)2-promoted reaction of C60 with easily available primary amines allows the concise preparation of aziridinofullerenes. Both alkyl and aryl amines are suitable in this reaction. Moreover, the Cu(OAc)2-promoted reaction of C60 with diamines affords C60-fused cyclic 1,2-diaminated fullerenes.

Graphical abstract: Cu(OAc)2-promoted reaction of [60]fullerene with primary amines or diamines
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