De novo synthesis of deoxy sugarvia a Wharton rearrangement†‡
Hua-Yu Leo Wang,George A. O'Doherty
Chemical Communications Pub Date : 08/18/2011 00:00:00 , DOI:10.1039/C1CC13837E
Abstract
A highly divergent synthesis of α-fuco-, α-6-deoxy-allo-, α-6-deoxy-altro-pyranosides has been achieved. This route utilizes a Wharton rearrangement as part of a new post-glycosylation transformation strategy.