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Direct observation of morphological evolution of a catalyst during carbon nanotube forest growth: new insights into growth and growth termination†
Jaegeun Lee,Hwan-Chul Kim,Jun Yeon Hwang,Bon-Cheol Ku,Dmitri N. Zakharov,Benji Maruyama,Eric A. Stach,Seung Min Kim
Nanoscale Pub Date : 12/15/2015 00:00:00 , DOI:10.1039/C5NR05547D
Abstract

In this study, we develop a new methodology for transmission electron microscopy (TEM) analysis that enables us to directly investigate the interface between carbon nanotube (CNT) arrays and the catalyst and support layers for CNT forest growth without any damage induced by a post-growth TEM sample preparation. Using this methodology, we perform in situ and ex situ TEM investigations on the evolution of the morphology of the catalyst particles and observe the catalyst particles to climb up through CNT arrays during CNT forest growth. We speculate that the lifted catalysts significantly affect the growth and growth termination of CNT forests along with Ostwald ripening and sub-surface diffusion. Thus, we propose a modified growth termination model which better explains various phenomena related to the growth and growth termination of CNT forests.

Graphical abstract: Direct observation of morphological evolution of a catalyst during carbon nanotube forest growth: new insights into growth and growth termination
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