Aerobic oxidative N-dealkylation of tertiary amines in aqueous solution catalyzed by rhodium porphyrins†‡
Zhen Ling,Lin Yun,Lianghui Liu,Bing Wu,Xuefeng Fu
Chemical Communications Pub Date : 11/26/2012 00:00:00 , DOI:10.1039/C2CC37263K
Abstract
Aerobic oxidative N-dealkylation of a variety of aliphatic tertiary amines and anilines catalyzed by rhodium(III) tetra (p-sulfonatophenyl) porphyrin ((TSPP)RhIII) is achieved in aqueous solution using dioxygen as the sole oxidant.
