Enantioselective catalysis with tropos ligands in chiral ionic liquids
Mike Schmitkamp,Dianjun Chen,Jürgen Klankermayer,Giancarlo Franciò
Chemical Communications Pub Date : 09/10/2007 00:00:00 , DOI:10.1039/B712068K
Abstract

Enantioselective homogeneous rhodium-catalysed hydrogenation using tropoisomeric biphenylphosphine ligands was accomplished in readily available chiral ionic liquids and the catalytic system could be reused after extraction with scCO2.

Graphical abstract: Enantioselective catalysis with tropos ligands in chiral ionic liquids