Polydimethylsiloxane (PDMS) was coated on multi-walled carbon nanotubes (MWCNTs) using a chemical vapour deposition method, and the PDMS-coated MWCNTs were well dispersed in various solvents without additional dispersants. Spin casting of the MWCNT-containing solution on a substrate pre-treated with PDMS-SiO₂ nanoparticles resulted in the formation of a uniform thin film. The resulting thin film containing MWCNTs showed high optical transparency, conductivity and superhydrophobicity. We demonstrated that such multifunctional thin films can also be prepared on flexible substrates.