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Facile syntheses of (+)-gabosines A, D, and E†‡
Tony K. M. Shing,Hau M. Cheng
Organic & Biomolecular Chemistry Pub Date : 10/16/2009 00:00:00 , DOI:10.1039/B911810A
Abstract

(+)-Gabosines A (12), D (4), and E (5), which share the same trihydroxycyclohexenone skeleton, were synthesized from enone 11 as the common intermediate. The key building block 11 was accessed by an intramolecular aldol cyclization of a diketone derived from D-glucose (8).

Graphical abstract: Facile syntheses of (+)-gabosines A, D, and E
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