960化工网
Ferromagnetic frustration in ternary nitride ZnFe3N
W. Wang,X. C. Kan,X. S. Liu,Z. T. Zhang,K. M. U. Rehman,C. C. Liu,M. Shezad
Physical Chemistry Chemical Physics Pub Date : 11/18/2020 00:00:00 , DOI:10.1039/D0CP03957H
Abstract

As a new antiperovskite nitride, ZnFe3N was synthesized and characterized by almost completely substituting iron atoms at corner positions of γ′-Fe4N. The magnetic interactions of the system with the space group Pm[3 with combining macron]m are fully investigated. The critical behavior was investigated based on the measured magnetic data around the ferromagnetic phase transition temperature. In this work, the values of critical exponents (β, γ and δ) were obtained systematically using the Kouvel–Fisher method in the critical region. The Widom scaling law (δ = 1 + γβ−1) and the scaling equation (m = f±(h)) were used to reveal the reliability of these values. The values of the critical exponents (β = 0.325, γ = 1.228, and δ = 4.778) are different from those predicted by the three-dimensional (3D) Heisenberg model and mean-field model, and are very close to those of the 3D-Ising model. Combined with ESR analysis, the spin clusters induced by changes in chemical bonds are considered to be the cause for the existence of an anisotropic short-range ordered state in this ferromagnetic system.

Graphical abstract: Ferromagnetic frustration in ternary nitride ZnFe3N
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