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Functionalized flexible MOFs as fillers in mixed matrix membranes for highly selective separation of CO2 from CH4 at elevated pressures†
Beatriz Zornoza,Alberto Martinez-Joaristi,Pablo Serra-Crespo,Carlos Tellez,Joaquin Coronas,Jorge Gascon,Freek Kapteijn
Chemical Communications Pub Date : 07/18/2011 00:00:00 , DOI:10.1039/C1CC13431K
Abstract

Mixed matrix membranes (MMMs) composed of a glassy polymer (polysulfone) and the flexible metal organic framework NH2-MIL-53(Al) exhibit excellent separation properties. In contrast to most reported membranes, CO2/CH4 separation selectivity increases with pressure, related to the flexibility of the filler.

Graphical abstract: Functionalized flexible MOFs as fillers in mixed matrix membranes for highly selective separation of CO2 from CH4 at elevated pressures
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