Highly enantioselective hydroformylation of dihydrofurans catalyzed by hybrid phosphine–phosphonite rhodium complexes†
Rosalba Bellini,Guillaume Berthon-Gelloz,Jarl Ivar van der Vlugt,Bas de Bruin,Joost N. H. Reek
Chemical Communications Pub Date : 01/18/2010 00:00:00 , DOI:10.1039/B924046B
Abstract
Unprecedented regio- and enantioselectivities (>91%) are reported for the Rh-catalyzed asymmetric hydroformylation of 2,3- and 2,5-dihydrofuran using tunable hybrid phosphine–phosphonite ligands.
