An NHC-CuCl functionalized metal–organic framework for catalyzing β-boration of α,β-unsaturated carbonyl compounds†,10.1039/C9DT00645A

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

An NHC-CuCl functionalized metal–organic framework for catalyzing β-boration of α,β-unsaturated carbonyl compounds†

Qingxia Yao,Xiufang Lu,Kaili Liu,Chao Ma,Jie Su,Cong Lin,Dacheng Li,Jianmin Dou,Junliang Sun,Wenzeng Duan

Dalton Transactions Pub Date : 03/26/2019 00:00:00 , DOI:10.1039/C9DT00645A

Abstract

A microporous metal–organic framework functionalized with in situ generated NHC-CuCl units (1) has been successfully synthesized from a novel imidazolium-containing ligand. In particular, the MOF 1 can catalyze β-boration of α,β-unsaturated carbonyl compounds, while the isoreticular version of 1 (1-im) modified with only imidazolium moiety cannot. This work demonstrates for the first time the heterogeneous catalysis of NHC-Cu(I)Cl within a MOF solid.