Interactions regulating the head-to-tail directed assembly of biological Janus rods†
A. C. Greene,M. Bachand,A. Gomez,G. D. Bachand
Chemical Communications Pub Date : 03/31/2017 00:00:00 , DOI:10.1039/C7CC01566F
Abstract

The directed, head-to-tail self-assembly of microtubule filaments may be generalized in the context of Janus colloidal rods. Specifically, their assembly at the tens of micron-length scale involves a careful balance between long-range electrostatic repulsion and short-range attractive forces. Here we show that the addition of counterion salts increases the rate of directed assembly by screening the electrostatic forces and enhancing the effectiveness of short-range interactions at the microtubule ends.

Graphical abstract: Interactions regulating the head-to-tail directed assembly of biological Janus rods