Ion current rectification and rectification inversion in conical nanopores: a perm-selective view†‡
Dmitry Momotenko,Fernando Cortés-Salazar,Jacques Josserand,Shujuan Liu,Yuanhua Shao,Hubert H. Girault
Physical Chemistry Chemical Physics Pub Date : 02/23/2011 00:00:00 , DOI:10.1039/C0CP02595J
Abstract

Ionic transport in charged conical nanopores is known to give rise to ion current rectification. The present study shows that the rectification direction can be inverted when using electrolyte solutions at very low ionic strengths. To elucidate these phenomena, electroneutral conical nanopores containing a perm-selective region at the tip have been investigated and shown to behave like classical charged nanopores. An analytical model is proposed to account for these rectification processes.

Graphical abstract: Ion current rectification and rectification inversion in conical nanopores: a perm-selective view