Alkene metathesis: the search for better catalysts
Prashant H. Deshmukh,Siegfried Blechert
Dalton Transactions Pub Date : 05/23/2007 00:00:00 , DOI:10.1039/B703164P
Abstract

Alkene metathesis catalyst development has made significant progress over recent years. Research in metathesis catalyst design has endeavoured to tackle three key issues: those of (i) catalyst efficiency and activity, (ii) substrate scope and selectivity—particularly stereoselective metathesis reactions—and (iii) the minimization of metal impurities and catalyst recycling. This article describes a brief history of metathesis catalyst development, followed by a survey of more recent research, with a particular emphasis on ruthenium catalysts.

Graphical abstract: Alkene metathesis: the search for better catalysts