Isolation and structural characterization of the most highly trifluoromethylated C70fullerenes: C70(CF3)18 and C70(CF3)20†
D. V. Ignat'eva,A. A. Goryunkov,N. B. Tamm,I. N. Ioffe,L. N. Sidorov,S. I. Troyanov
New Journal of Chemistry Pub Date : 11/29/2012 00:00:00 , DOI:10.1039/C2NJ40959C
Abstract
One isomer of C70(CF3)18 and two isomers of C70(CF3)20 have been isolated from the products of the trifluoromethylation of C70; their molecular structures were determined by single crystal X-ray crystallography and are discussed in terms of their addition patterns and relative formation energies.
