960化工网
Nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source†
Xue-Ping Wen,Yu-Ling Han,Jian-Xin Chen
RSC Advances Pub Date : 09/21/2017 00:00:00 , DOI:10.1039/C7RA08009C
Abstract

The nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source is developed. The procedure can prepare both tertiary and secondary amides, and is applicable to various carbamoylsilanes and aryl halides containing different functional groups. The types and the relative position of substituents on the aryl ring impact the coupling efficiency.

Graphical abstract: Nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source
平台客服
平台客服
平台在线客服