Adaptability of the metal(iii,iv) 1,2,3-trioxobenzene rod secondary building unit for the production of chemically stable and catalytically active MOFs†,10.1039/C7CC04215A

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Adaptability of the metal(iii,iv) 1,2,3-trioxobenzene rod secondary building unit for the production of chemically stable and catalytically active MOFs†

Georges Mouchaham,Brian Abeykoon,Sergio Navalon,Andrea Santiago-Portillo,Maame Affram,Nathalie Guillou,Charlotte Martineau,Hermenegildo Garcia,Alexandra Fateeva

Chemical Communications Pub Date : 06/15/2017 00:00:00 , DOI:10.1039/C7CC04215A

Abstract

The use of a 5,10,15,20-tetrakis(3,4,5-trihydroxyphenyl)porphyrin has yielded a new MOF based on M-1,2,3-trioxobenzene chains that can be made of M = Zr(IV) or RE(III) (RE = rare earth), showing a very high and limited chemical stability, respectively. The robust metallated Zr-analogue, Co-MIL-173(Zr), has proven to be a heme-like heterogeneous catalyst suitable for aerobic oxidation of hydrocarbons.