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An expedient synthesis of oxazolones using a cellulose supported ionic liquid phase catalyst
Rajanikant Kurane,Sharanabasappa Khanapure,Dolly Kale,Rajashri Salunkhe,Gajanan Rashinkar
RSC Advances Pub Date : 04/26/2016 00:00:00 , DOI:10.1039/C6RA03873E
Abstract

A novel cellulose supported ionic liquid phase catalyst containing hydroxide ions ([CellFemImi]OH) has been synthesized by covalent anchoring of 1-N-ferrocenylmethyl imidazole in the functionalized cellulose matrix followed by an anion metathesis reaction. The [CellFemImi]OH was characterized by various techniques including FT-IR, FT-Raman, 13C solid state NMR, X-ray diffraction, energy dispersive X-ray (EDX) analysis, field emission scanning electron microscopy (FESEM) and thermogravimetric analysis. The [CellFemImi]OH was effectively employed as a heterogeneous catalyst in the synthesis of oxazolones by cyclocondensation of aryl aldehydes with hippuric acid in the presence of acetic anhydride.

Graphical abstract: An expedient synthesis of oxazolones using a cellulose supported ionic liquid phase catalyst
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