Rapid carbonylative coupling reactions using palladium(i) dimers: applications to 11CO-radiolabelling for the synthesis of PET tracers†,10.1039/C1OB05268C

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Rapid carbonylative coupling reactions using palladium(i) dimers: applications to 11CO-radiolabelling for the synthesis of PET tracers†

Gabriella Buscemi,Philip W. Miller,Nicholas J. Long,Jan Passchier,Ramon Vilar

Organic & Biomolecular Chemistry Pub Date : 02/25/2011 00:00:00 , DOI:10.1039/C1OB05268C

Abstract

Palladium dimers with sterically hindered phosphines have been shown to be excellent pre-catalysts for the aminocarbonylation of aryl halides to yield amides and one of them has been successfully employed as a pre-catalyst for the synthesis of ¹¹C-radiolabelled amides for PET imaging.