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Response of the potential of a gold electrode to elastic strain
D. Kramer,S. Mohanan,U. Herr
Physical Chemistry Chemical Physics Pub Date : 08/21/2009 00:00:00 , DOI:10.1039/B913448D
Abstract

We describe the measurement of the response, ς, of the potential of a metal electrode to elastic strain under open circuit conditions. The experimental response exhibits a frequency dependence due to Faraday loss currents, which become negligible beyond 30 Hz. For a (111)-textured gold film the experimental value at higher frequency, ς = −1.83 V, compares well with the intrinsic value of Au(111) predicted by recent ab initio computation.

Graphical abstract: Response of the potential of a gold electrode to elastic strain
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