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Ruthenium-catalyzed carbonylation of allene: direct synthesis of methacrylates and methacrylamides
Da-Yang Zhou,Eiji Yoneda,Kiyotaka Onitsuka,Shigetoshi Takahashi
Chemical Communications Pub Date : 10/31/2002 00:00:00 , DOI:10.1039/B205817K
Abstract

Carbonylation reactions of allene in alcohols and amines in the presence of a ruthenium carbonyl catalyst under mild conditions gave methacrylates and methacrylamides, respectively, in good yields with an atom economy of 100%.

Graphical abstract: Ruthenium-catalyzed carbonylation of allene: direct synthesis of methacrylates and methacrylamides
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