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Stereoselective synthesis of (+)-boronolide and its 8-epimer
Shou-Gang Hu,Tai-Shan Hu,Yu-Lin Wu
Organic & Biomolecular Chemistry Pub Date : 07/23/2004 00:00:00 , DOI:10.1039/B406397J
Abstract

Starting from readily available carbohydrates the synthesis of 8-epi-(+)-boronolide 19 and (+)-boronolide 1 was achieved with diastereoselective propargylation of α-oxygenated aldehyde as a key step.

Graphical abstract: Stereoselective synthesis of (+)-boronolide and its 8-epimer
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