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Strain heterogeneity in sheared colloids revealed by neutron scattering
Kevin Chen,Bin Wu,Lilin He,Gregory S. Smith,Changwoo Do,Gaibo Zhang,Yangyang Wang
Physical Chemistry Chemical Physics Pub Date : 02/07/2018 00:00:00 , DOI:10.1039/C7CP07197C
Abstract

Recent computational and theoretical studies have shown that the deformation of colloidal suspensions under a steady shear is highly heterogeneous at the particle level and demonstrate a critical influence on the macroscopic deformation behavior. Despite its relevance to a wide variety of industrial applications of colloidal suspensions, scattering studies focusing on addressing the heterogeneity of the non-equilibrium colloidal structure are scarce thus far. Here, we report the first experimental result using small-angle neutron scattering. From the evolution of strain heterogeneity, we conclude that the shear-induced deformation transforms from nearly affine behavior at low shear rates, to plastic rearrangements when the shear rate is high.

Graphical abstract: Strain heterogeneity in sheared colloids revealed by neutron scattering
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