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An all-inorganic polyoxometalate–polyoxocation chemical garden†
Laurie J. Points,Geoffrey J. T. Cooper,Anne Dolbecq,Pierre Mialane,Leroy Cronin
Chemical Communications Pub Date : 12/07/2015 00:00:00 , DOI:10.1039/C5CC09536K
Abstract

Herein, we show it is possible to produce wholly inorganic chemical gardens from a cationic polyoxometalate (POM) seed in an anionic POM solution, demonstrating a wholly POM-based chemical garden system that produces architectures over a wide concentration range. Six concentration dependent growth regimes have been discovered and characterized: clouds, membranes, slugs, tubes, jetting and budding.

Graphical abstract: An all-inorganic polyoxometalate–polyoxocation chemical garden
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