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Sustainable fabrication of ultralong Pb(OH)Br nanowires and their conversion to luminescent CH3NH3PbBr3 nanowires†
Yangchun Yu,Sanam Attique,Jiahui Hou,Fangying Jun,Yiquan Xie,Lebao Mao,Xiaoqing Yu,Xiuhua Zhang,Shengfu Wang,Chongchong Wu,Bingqiang Cao,Shikuan Yang
Green Chemistry Pub Date : 09/13/2021 00:00:00 , DOI:10.1039/D1GC02073K
Abstract

The fabrication of lead halide perovskites involves different types of organic solvents, which are not only harmful to the environment but also expensive. Herein, we present an ultimately green process to prepare CH3NH3PbBr3 (MAPbBr3) nanowires without using any organic solvents, acids, and alkalis. According to the formula of Pb(OH)Br, only PbBr2 and water are used to synthesize Pb(OH)Br. Subsequently, the Pb(OH)Br nanowires are converted into MAPbBr3 nanowires via a thermal evaporation technique (i.e., exposing Pb(OH)Br nanowires to MABr vapor). The prepared MAPbBr3 nanowires show comparable optical properties to those prepared using organic solvents. Such an ultimately green fabrication method can alleviate the environmental concerns and reduce the cost of perovskite commercialization.

Graphical abstract: Sustainable fabrication of ultralong Pb(OH)Br nanowires and their conversion to luminescent CH3NH3PbBr3 nanowires
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