The first total synthesis of (+)-goniothalesacetate and syntheses of (+)-altholactone, (+)-gonioheptolide A, and (−)-goniofupyrone by an asymmetric acetate aldol approach†,10.1039/C5OB01598G

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The first total synthesis of (+)-goniothalesacetate and syntheses of (+)-altholactone, (+)-gonioheptolide A, and (−)-goniofupyrone by an asymmetric acetate aldol approach†

Sandeep AnkiReddy,Praveen AnkiReddy,Gowravaram Sabitha

Organic & Biomolecular Chemistry Pub Date : 08/24/2015 00:00:00 , DOI:10.1039/C5OB01598G

Abstract

The first stereoselective total synthesis of (+)-goniothalesacetate and total synthesis of several bioactive styryl lactones, (+)-altholactone, (+)-gonioheptolide A, and (−)-goniofupyrone have been achieved from an advanced intermediate, which can be derived from L-(+)-DET.