The mechanism of activation of amidobenzylidene ruthenium chelates – latent catalysts of olefin metathesis†
Szymon Rogalski,Patrycja Żak,Natalia Tadeuszyk,Krystian Pyta,Piotr Przybylski,Cezary Pietraszuk
Dalton Transactions Pub Date : 01/09/2017 00:00:00 , DOI:10.1039/C6DT04290B
Abstract

Amidobenzylidene ruthenium chelates – latent catalysts of olefin metathesis can be easily activated by the addition of Brønsted or Lewis acids. Their activation in the presence of hydrogen chloride involves the formation of catalytically active trans-dichloro carbamatobenzylidene ruthenium chelates.

Graphical abstract: The mechanism of activation of amidobenzylidene ruthenium chelates – latent catalysts of olefin metathesis