The oxidation of Ni(ii) N-confused porphyrins (NCPs) with azo radical initiators and an unexpected intramolecular nucleophilic substitution reactionvia a proposed Ni(iii) NCP intermediate†
Chemical Communications Pub Date : 05/15/2009 00:00:00 , DOI:10.1039/B904615A
Abstract
The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators resulted in an unexpected intramolecular nucleophilic substitution reactionvia a proposed Ni(III) NCP intermediate, which could be detected by HRMS.
