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An NMR study on a pseudo-intramolecular transacylation reaction of an α-aryl-β-keto ester†
Sho Hirai,Haruyasu Asahara,Shotaro Hirao,Jun Sawayama,Ryuichi Sugimoto,Kazuhiko Saigo,Nagatoshi Nishiwaki
RSC Advances Pub Date : 11/14/2013 00:00:00 , DOI:10.1039/C3RA45568H
Abstract

The pseudo-intramolecular transacylation reaction efficiently proceeds like an intramolecular reaction, even though it is actually an intermolecular reaction. We have obtained valuable insights by monitoring the reaction by 1H NMR spectroscopy.

Graphical abstract: An NMR study on a pseudo-intramolecular transacylation reaction of an α-aryl-β-keto ester
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