An NHC–phosphinidenyl as a synthon for new group 13/15 compounds†,10.1039/C7CC04422D

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An NHC–phosphinidenyl as a synthon for new group 13/15 compounds†

Otfried Lemp,Markus Balmer,Kevin Reiter,Florian Weigend,Carsten von Hänisch

Chemical Communications Pub Date : 06/22/2017 00:00:00 , DOI:10.1039/C7CC04422D

Abstract

The parent phosphinidene SIMesPH (1) (SIMes = 1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene) was treated with benzyl potassium to form the metalated species SIMesPK (2), which was used as a synthon for the new group 13/15 cycles and cage compounds [SIMesPGatBu₂]₂ (3), [SIMesP(GatBu₂)₂Cl] (4) and [K(SIMesP)₃AltBu] (5).