An eleven-vertex deltahedron with hexacapped trigonal bipyramidal geometry†
C. W. Liu,Ping-Kuei Liao,Ching-Shiang Fang,Jean-Yves Saillard,Samia Kahlal,Ju-Chun Wang
Chemical Communications Pub Date : 04/12/2011 00:00:00 , DOI:10.1039/C1CC10168D
Abstract
The first elemental cluster with hexacapped trigonal bipyramidal geometry is revealed in the luminescent undecanuclear silver complex which is stabilized by nine dithiocarbamate ligands and has an interstitial hydride. The hydride position within the Ag11 cage is confirmed by a DFT investigation.
