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Anion directed conformational diversities of an arene based hexa-amide receptor and recognition of the [F4(H2O)6]4− cluster†
Sourav Chakraborty,Ranjan Dutta,Bryan M. Wong,Pradyut Ghosh
RSC Advances Pub Date : 11/13/2014 00:00:00 , DOI:10.1039/C4RA10795K
Abstract

A benzene platform based new hexa-amide receptor (L) has shown conformational diversities via isolation of aaabbb (A), aabaab (B) and aaaaaa (C) conformers upon recognition of acetate, nitrate and hydrated-fluoride [F4(H2O)6]4− respectively in the solid state. Solution and DFT calculation studies show fluoride binding selectivity of L.

Graphical abstract: Anion directed conformational diversities of an arene based hexa-amide receptor and recognition of the [F4(H2O)6]4− cluster
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