Allosteric function facilitates template assisted olefin metathesis†
Rie Wakabayashi,Yohei Kubo,Osamu Hirata,Masayuki Takeuchi,Seiji Shinkai
Chemical Communications Pub Date : 10/20/2005 00:00:00 , DOI:10.1039/B512805F
Abstract

Template assisted olefin metathesis of an allosteric host 1b to give the corresponding bicyclic compound 1c was achieved and 1c can allosterically bind the template guest diamines, 2 and 3 with different affinity and cooperativity.

Graphical abstract: Allosteric function facilitates template assisted olefin metathesis